Table 2 1H and 13C NMR data assignments of P44 compound in CD3OD at 298K. See Fig. 2b for numbering of hydrogen and carbon atoms
From: Production of vineomycin A1 and chaetoglobosin A by Streptomyces sp. PAL114
1H and 13C number | 1H chemical shift, ppm | 13C chemical shift, ppm |
|---|---|---|
1 | 1.33 | 14.04 |
2 | 4.61 | 70.21 |
3 | – | 197.28 |
4 | 7.04 | 144.19 |
5 | 6.08 | 126.13 |
6 | 5.34 | 95.13 |
7 | 1.25 | 16.10 |
8 | 4.24 | 66.33 |
9 | 3.71 | 76.40 |
10 | 1.51–1.69 | 24.40 |
11 | 1.97 | 23.93 |
12 | 5.25 | 92.10 |
13 | 1.39 | 24.90 |
14 | – | 81.95 |
15 | 1.99–2.32 | 42.61 |
16 | – | 79.80 |
17 | – | 79.50 |
18 | – | 205.28 |
19 | 2.73–2.93 | 50.18 |
20 | 6.90 | 116.65 |
21 | 6.41 | 145.40 |
22 | – | 139.03 |
23 | – | 138.50 |
24 | – | 182.30 |
25 | – | 137.68 |
26 | – | 130.97 |
27 | – | 182.30 |
28 | – | 157.40 |
29 | – | 114.00 |
30 | 7.89 | 132.84 |
31 | 7.62 | 118.63 |
32 | 1.38 | 17.39 |
33 | 3.56 | 75.18 |
34 | 3.15 | 86.45 |
35 | 3.82 | 71.13 |
36 | 1.41–2.49 | 39.28 |
37 | 4.92 | 70.98 |
38 | 1.23 | 15.72 |
39 | 4.37 | 67.34 |
40 | 3.76 | 76.28 |
41 | 1.99–2.11 | 23.93 |
42 | 1.51–1.69 | 24.40 |
43 | 5.01 | 98.92 |
44 | 1.33 | 14.04 |
45 | 4.61 | 70.21 |
46 | – | 197.34 |
47 | 7.02 | 144.09 |
48 | 6.09 | 126.18 |
49 | 5.35 | 95.13 |