Table 3 1H and 13C NMR data assignments of the P40 compound in CD3OD at 298 K. See Fig. 3b for numbering of hydrogen and carbon atoms
From: Production of vineomycin A1 and chaetoglobosin A by Streptomyces sp. PAL114
1H and 13C number | 1H chemical shift, ppm | 13C chemical shift, ppm |
|---|---|---|
1 | 6.95 | 124.2 |
2 | – | 108.0 |
3 | – | 127.5 |
4 | – | 136.6 |
5 | 7.26 | 111.3 |
6 | 7.49 | 118.1 |
7 | 7.00 | 118.4 |
8 | 7.03 | 120.7 |
9 | 2.84 | 32.1 |
10 | 3.91 | 57.7 |
11 | 2.89 | 46.4 |
12 | – | 63.1 |
13 | – | 174.3 |
14 | 1.73 | 36.3 |
15 | – | 58.0 |
16 | 2.78 | 62.1 |
17 | 2.05 | 48.9 |
18 | 1.08 | 12.1 |
19 | 1.30 | 18.4 |
20 | 6.04 | 128.3 |
21 | 5.13 | 132.7 |
22 | 2.00–2.29 | 41.3 |
23 | 2.47 | 31.8 |
24 | 5.53 | 139.2 |
25 | – | 132.3 |
26 | 5.00 | 81.5 |
27 | – | 200.5 |
28 | 6.13 | 131.7 |
29 | 7.27 | 134.4 |
30 | – | 197.3 |
31 | 1.00 | 19.8 |
32 | 1.33 | 9.5 |